1. Louis, Dauphin of France (November 1, 1661 – April 14, 1711), married Maria Anna Victoria of Bavaria and had issue
2. Anne Élisabeth of France (November 18, 1662 – December 30, 1662)
3. Marie Anne of France (November 16, 1664 – December 26, 1664)
4. Marie Thérèse of France (June 10, 1667 – March 1, 1672)
5. Philippe Charles, Duke of Anjou (December 5, 1668 – July 10, 1671)
6. Louis François, Duke of Anjou (June 14, 1672 – November 4, 1672)
7. Louis, the Grand Dauphin (November 1, 1661 – April 14, 1711), had issue
8. Louis Alexandre, Prince of France (June 6, 1678 – December 1, 1711)
9. Louis, Duke of Burgundy (August 6, 1682 – February 18, 1712), married Maria Adelaide of Savoy and had issue
10. Philippe, Duke of Anjou (December 19, 1683 – July 9, 1746), married Maria Luisa Gabriella of Savoy and had issue
11. Charles, Duke of Berry (August 31, 1686 – May 5, 1714)
12. Stillborn Son (died in March 1688)
13. Marie Adélaïde of Savoy (December 6, 1685 – February 12, 1712), married Louis, Duke of Burgundy, and had issue
14. Marie Louise Gabrielle of Savoy (August 17, 1688 – September 12, 1688)
15. Louis Alphonse of France (July 31, 1689 – April 14, 1690)
16. Stillborn twin princes (November 3, 1689)